Subtract the identities and gather the D terms: D(Q−Q′)=R′−R.
If Q=Q′, the left side is a nonzero polynomial of degree at least degD, because degrees add under multiplication. But the right side, a difference of two polynomials each zero or of degree below degD, is zero or of degree below degD. No polynomial can be both, so Q=Q′.
D(Q−Q′)=0 ⇒ R′−R=0
Then the remainders agree too. The quotient-remainder pair is unique, which is why we may speak of THE quotient and THE remainder.