First, note the range. A binomial coefficient (kn) is only defined for k≤n, and the larger index on offer here is 5, so n≥5 before any algebra begins.
Write each side with the closed form and set them equal:
3!(n−3)!n!=5!(n−5)!n!
The n! on top is the same on both sides, so the denominators must match: 3!(n−3)!=5!(n−5)!. Peel two factors off the larger factorial, using (n−3)!=(n−3)(n−4)(n−5)!, and the (n−5)! cancels as well:
6(n−3)(n−4)=120⟹(n−3)(n−4)=20
Since n≥5, both n−3 and n−4 are positive, and the only two consecutive positive whole numbers with product 20 are 5 and 4. So n−3=5, giving n=8.
Check it on row 8, which is 1, 8, 28, 56, 70, 56, 28, 8, 1: the entries at k=3 and k=5 are both 56. The symmetry (kn)=(n−kn) is the reason to expect a solution at all, since 3 and 5 are reflections of each other exactly when 3+5=n.